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1,4-Naphthalenedione, 2-chloro-3-[(4-methoxyphenyl)amino]-, also known as 2-chloro-3-(4-methoxyanilino)naphthalene-1,4-dione, is a chemical compound with the molecular formula C17H13ClN2O3. It is a derivative of 1,4-naphthoquinone, featuring a chloro group at the 2-position, a 4-methoxyphenylamine group at the 3-position, and a carbonyl group at both the 1 and 4 positions. 1,4-Naphthalenedione, 2-chloro-3-[(4-methoxyphenyl)amino]- is an organic molecule with potential applications in the synthesis of pharmaceuticals and other organic compounds. Its structure and properties make it a versatile intermediate in various chemical reactions, particularly in the development of new drugs and materials.

22359-32-6

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22359-32-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 22359-32-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,2,3,5 and 9 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 22359-32:
(7*2)+(6*2)+(5*3)+(4*5)+(3*9)+(2*3)+(1*2)=96
96 % 10 = 6
So 22359-32-6 is a valid CAS Registry Number.

22359-32-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-chloro-3-(4-methoxyanilino)naphthalene-1,4-dione

1.2 Other means of identification

Product number -
Other names 3-<p-Anisidino>-2-chlor-1,4-naphthochinon

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:22359-32-6 SDS

22359-32-6Relevant academic research and scientific papers

Thermolysis of 2-azido-3-(R-anilino)-1,4-naphthoquinones. Nitrene insertion versus hydrogen abstraction

Cárdenas-Chaparro, Agobardo,Leyva, Elisa,Loredo-Carrillo, Silvia E.,Martínez-Richa, Antonio,Platz, Matthew S.

supporting information, (2020/03/03)

2-chloro-3-(R-anilino)-1,4-naphthoquinones react with sodium azide upon refluxing in DMF. The thermochemistry of 2-azido-3-(R-anilino)-1,4-naphthoquinone is strongly modified by the substituent on aniline. Having an strong electron-donor like O-R results

Crystallographic evidence for resonance assisted H-Bonding effect in selective colorimetric detection of cyanide by arylamino-naphthoquinones

Rajalakshmi,Jayasudha,Ciattini, Samuele,Chelazzi, Laura,Elango, Kuppanagounder P.

, p. 259 - 268 (2019/06/19)

Five new chemo-receptors, based on arylamino-naphthoquinone, possessing electron donating and electron withdrawing substituents have been prepared by single step green method. These receptors are found to be highly selective and sensitive towards cyanide

Composition for Distructing Microalgae

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Paragraph 0469-0472, (2017/09/05)

The present invention relates to a composition for destroying microalgae, more specifically, to a composition for destroying microalgae containing naphthoquinone compounds having a specific exchange group. The composition for destroying microalgae, according to the present invention, can prevent green tide and red tide by being processed in areas such as cultivation facilities for microalgae, areas in which the green tide or the red tide occur, or areas expected to occur the green tide or the red tide.

Charge transfer facilitated direct electrophilic substitution in phenylaminonaphthoquinones: Experimental, theoretical and electrochemical studies

Satheshkumar,Ganesh,Elango, Kuppanagounder P.

, p. 993 - 1003 (2014/03/21)

A simple and effective synthetic protocol to introduce electron withdrawing substitutents (Br and NO2) in the phenyl ring of 2-(p-R-phenylamino)-3-chloro-1,4-naphthoquinones (where R = H, Me, OMe, F and Cl; 1a-e) has been demonstrated using the

Synthesis and characterization of nitrogen and sulfur containing 1,4-naphthoquinones

Sayil, Cigdem,Kurban, Semih,Ibis, Cemil

, p. 1855 - 1867 (2013/11/06)

New N,S-disubstituted naphthoquinones were synthesized by reactions of S- and N-nucleophiles with 2,3-dichloro-1,4-naphthoquinone. 2-(Hexadecylthio)-3- (phenylamino)-naphthalene-1,4-dione 5a was synthesized by reaction of 2-chloro-3-(phenylamino)-naphthal

Spectroscopic and theoretical studies on the nucleophilic substitution of 2,3-dichloronaphthoquinone with para-substituted anilines in solid state via initial charge transfer complexation

Satheshkumar, Angupillai,Elango, Kuppanagounder P.

, p. 378 - 383,6 (2012/12/12)

Various spectroscopy techniques (UV-Vis, DRS, FT-IR, 1H NMR, LC-MS) and theoretical computations have been employed to investigate the mechanism of the nucleophilic substitution reaction of 2,3- dichloronaphthoquinone (DCNQ) with para-substitut

Biological evaluation of donor-acceptor aminonaphthoquinones as antitumor agents

Benites, Julio,Valderrama, Jaime A.,Bettega, Karina,Pedrosa, Rozangela Curi,Calderon, Pedro Buc,Verrax, Julien

experimental part, p. 6052 - 6057 (2011/01/13)

Several members of the phenylamino-1,4-naphthoquinone series were prepared in order to investigate structure-activity relationships (SAR) and to explore the antitumor effects associated with this scaffold. The cytotoxic effects of the aminoquinones (ECsu

Direct nitration of 3-arylamino-2-chloro-1,4-naphthoquinones

Win, Thida,Yerushalmi, Sarit,Bittner, Shmuel

, p. 1631 - 1634 (2007/10/03)

A convenient two-step synthesis of mononitro and dinitro derivatives of the title compounds is reported. The Michael type addition of aromatic amines to 2,3-dichloro-1,4-naphthoquinone, is followed by mixed acids nitration to yield nitro aromatic quinones

A new synthesis of quinoxaline, imidazolidine, indole and carbazole derivatives

Aly,Hassan,Mohamed,Mourad

, p. 282 - 287 (2007/10/03)

Reactions of bis-benzalethylenediamine (1), N,N'-bis(aryl)- and N,N'-bis(cyclohexyl)ethane-1,2-diylidenediamines as well as N,N'-bis(aryl)benzene-1,4-diyldimethylidenediamines 2 with benzo- and naphthoquinones as well as α,β-unsaturated ketones such as 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ); 2,3,5,6-tetrachloro-1,4-benzoquinone (CHl-p); 3,4,5,6-tetrachloro-1,2-benzoquinone (CHl-o); 2,3-dichloro-1,4-naphthoquinone (DCNQ); 2,3-dicyano- l,4-naphthoquinone (DCNQ) and dicyanomethyleneindane-1,3-dione (CNIND) afforded quinoxaline, pyrazinoquinoxaline, imidazolidine, indole and carbazole derivatives as well as arylaminobenzo-, and napthoquinones.

Iodination and chlorination of 2-/4-arylamino-1,4-/1,2-naphthoquinones with alkylhalides and DMSO

Kallmayer,Doerr

, p. 479 - 485 (2007/10/03)

2-/4-Arylamino-1,4-/1,2-naphthoquinones 10/13 are chlorinated with tert-butylbromide, DMSO and calcium chloride to give 2-/4-arylamino-3-chloro-1,4-/1,2-naphthoquinones 11A/14A. The iodination with tert-butylbromide, DMSO and potassium iodide give 2-/4-arylamino-3-iodo-1,4-/1,2-naphthoquinones 11C/14C.

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