2237-18-5Relevant academic research and scientific papers
Bimetal complex with aryloxy ether skeleton, and preparation method and application thereof
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Paragraph 0129; 0154-0155, (2020/11/26)
The invention provides a bimetallic complex with an aryloxy ether skeleton, and a preparation method and application of the bimetallic complex. The bimetallic complex has a structural expression as shown in the specification. A catalytic system of the bimetallic complex shows very good catalytic activity and thermal stability when being used for catalyzing olefin homopolymerization or olefin/alphaolefin copolymerization reactions, and a polymerization product generated by catalysis has relatively high molecular weight and a high alpha-olefin insertion rate and has a very good industrial application prospect.
The synthesis and conformation of oxygenated trianglimine macrocycles
Kuhnert, Nikolai,Lopez-Periago, Ana,Rossignolo, Giulia M.
, p. 524 - 537 (2007/10/03)
The synthesis of series of D2h and C2v symmetric oxygenated aromatic dicarboxaldehydes, using dilithiation methodology, is described along with their reactivity in the [3 + 3] cyclocondensation reaction with (1R,2R)-diaminocyclohexane to give oxygenated trianglimine macrocycles. Macrocycles derived from C2v symmetric dialdehydes give macrocycles with a stereogenic aromatic plane with complete diastereocontrol, as a mixture of retainers.
