224-56-6Relevant articles and documents
A facile synthesis of functionalized 7,8-diaza[5]helicenes through an oxidative ring-closure of 1,1'-binaphthalene- 2,2'-diamines (BINAMs)
Takeda, Youhei,Okazaki, Masato,Maruoka, Yoshiaki,Minakata, Satoshi
supporting information, p. 9 - 15 (2015/01/30)
A facile and moderately functional-group-tolerant synthetic method for the preparation of 7,8-diaza[5]helicenes has been developed. It comprises of an oxidative ring-closing process of 1,1'-binaphthalene-2,2'-diamine (BINAM) derivatives with a chlorinecontaining oxidant (t - BuOCl) in the presence of a base (2,6-lutidine). In addition the basic physicochemical properties of newly synthesized compounds have been investigated.