22410-44-2Relevant articles and documents
Method for preparing fluorine-containing ether
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Paragraph 0082-0083, (2019/07/29)
The invention relates to a 'method for preparing fluorine-containing ether', and belongs to the field of chemical synthesis. The method comprises the steps that under a nitrile solvent condition, carbonyl fluoride, trifluoroacetyl fluoride, pentafluoropropionyl fluoride, heptafluoro-n-butyryl fluoride, heptafluoro-iso-butyryl fluoride and other acyl fluorides are taken as raw materials to have anaddition reaction with metal fluorides to obtain perfluoroalkoxide, then under water catalysis, the perfluoroalkoxide and a low-toxic or even non-toxic harmless alkylating agent are subjected to an alkylation reaction to obtain the fluorine-containing ether. The method for preparing the fluorine-containing ether has the advantages that not only is the reaction condition mild, the yield of the fluorine-containing ether is high, but also the low-toxic or even non-toxic harmless alkylating agent is taken as a safe alkylation agent, the process is safe and reliable, and effective separation can beperformed by an ordinary distillation means in the industry.
New synthetic method of alkyl perfluoroalkyl ethers
Tamura, Masanori,Takubo, Seij,Quan, Heng-Dao,Sekiya, Akira
, p. 343 - 344 (2007/10/03)
vic-Difluorination of alkyl perfluoroenol ethers proceeded with high- valence metal fluoride, such as cobalt (III) fluoride and potassium tetrafluorocobaltate, in good yields to afford alkyl perfluoroalkyl ethers.