22414-62-6

Basic information

• Product Name: TRI-N-BUTYL SILYL METHACRYLATE
• Synonyms: TRI-N-BUTYL SILYL METHACRYLATE;2-Propenoic acid,2-methyl-, tributylsilyl ester
• CAS NO: 22414-62-6
• Molecular Formula: C₁₆H₃₂O₂Si
• Molecular Weight: 284.51
• Mol File: 22414-62-6.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 314.513 °C at 760 mmHg
• Flash Point: 119.714 °C
• Appearance: /
• Density: 0.871 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.441
• CAS DataBase Reference: TRI-N-BUTYL SILYL METHACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: TRI-N-BUTYL SILYL METHACRYLATE(22414-62-6)
• EPA Substance Registry System: TRI-N-BUTYL SILYL METHACRYLATE(22414-62-6)

Safety Data

• Hazardous Substances Data: 22414-62-6(Hazardous Substances Data)

Usage

General Description

TRI-N-BUTYL SILYL METHACRYLATE is a chemical compound used in the synthesis of functional materials such as polymers and coatings. It is a type of methacrylate monomer, which means it has a reactive double bond that allows it to be polymerized to form a plastic material. TRI-N-BUTYL SILYL METHACRYLATE is often used as a crosslinking agent in the production of acrylic resins, which are widely used in adhesives, sealants, and coatings. Its tri-n-butyl silyl group provides additional hydrophobic and sterically hindered properties to the resulting polymers, making them resistant to environmental degradation and improving their mechanical properties. TRI-N-BUTYL SILYL METHACRYLATE is also used in photolithography processes and as a co-monomer in the production of photoresists for microelectronics applications.

InChI:InChI=1/C16H32O2Si/c1-6-9-12-19(13-10-7-2,14-11-8-3)18-16(17)15(4)5/h4,6-14H2,1-3,5H3

Upstream product

• 79-41-4 poly(methacrylic acid) 
• 15811-64-0 Tributylmethoxysilane 
• 760-93-0 methacryloyl anhydride 
• 22192-48-9 tri-n-butylsilyl acetate 
• 18388-85-7 tributylsilanol 
• 998-41-4 tributylsilane 

Relevant articles and documents

Two new catalysts for the dehydrogenative coupling reaction of carboxylic acids with silanes - Convenient methods for an atom-economical preparation of silyl esters

Tris(triphenylphosphine)cuprous chloride [Cu(PPh3)3Cl] has been found to be an efficient catalyst for the dehydrosilylation of carboxylic acids with silanes. In the presence of 4 mol% Cu(PPh3)3Cl, dehydrosilylation reactions in acetonitrile afforded the corresponding silyl esters at 80°C in good yields. It was noted that triphenylphosphine itself also functions as an adequate catalyst for the reaction. Copyright Taylor & Francis Group, LLC.

Convenient synthesis of tributylsilyl methacrylate

To replace antifouling paints containing organotin compounds and to develop self-polishing coatings free of toxicity, we describe here the synthesis of a new polymerizable molecule containing silicon: tributylsilyl methacrylate. Copyright Taylor & Francis Group, LLC.

Process for the production of silyl carboxylate monomers

A process for the production of hydrocarbyl silyl unsaturated carboxylates of formula (I) is described, wherein n represents a number of dihydrocarbylsiloxane units from 0 to 1000. The process includes the reaction of an unsaturated carboxylic acid of formula (II) with a hydrocarbyl silyl compound of formula (III) the said reaction being carried out in the presence of a silaphilic catalyst.