22414-68-2

Basic information

• Product Name: 2-Nonylacrylaldehyde
• Synonyms: 2-Methyleneundecanal;2-Nonylacrylaldehyde;Undecanal, 2-methylene-
• CAS NO: 22414-68-2
• Molecular Formula: C₁₂H₂₂O
• Molecular Weight: 182.3025
• Mol File: 22414-68-2.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 260.5°Cat760mmHg
• Flash Point: 100.8°C
• Appearance: /
• Density: 0.833g/cm³
• Vapor Pressure: 0.0122mmHg at 25°C
• Refractive Index: 1.437
• CAS DataBase Reference: 2-Nonylacrylaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Nonylacrylaldehyde(22414-68-2)
• EPA Substance Registry System: 2-Nonylacrylaldehyde(22414-68-2)

Safety Data

• Hazardous Substances Data: 22414-68-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H22O/c1-3-4-5-6-7-8-9-10-12(2)11-13/h11H,2-10H2,1H3

Upstream product

• 112-44-7 undecylaldehyde 
• 33797-51-2 eschenmoser's salt 
• 50-00-0 formaldehyd 

Downstream Products

• 110-41-8 2-methylundecanal 
• 71582-80-4 (-)-malyngolide 
• 880480-05-7 1-Diazo-5-methylene-1-(2,4,6-trimethyl-benzenesulfonyl)-tetradecan-2-one 
• 880480-06-8 5-Methylene-1-(2,4,6-trimethyl-benzenesulfonyl)-tetradecan-2-one 

Relevant articles and documents

Enantioselective total synthesis of δ-lactonic marine natural products, (+)-tanikolide and (-)-malyngolide, via RCM reaction

Enantioselective total synthesis of δ-lactonic marine natural products, (+)-tanikolide and (-)-malyngolide isolated from Lyngbya majuscula, was achieved by using the Sharpless asymmetric epoxidation and a ring-closing metathesis, as key reactions.

COMPOSITIONS COMPRISING ODORANTS

The present invention relates to odorous 2- and/or 3-substituted 3-(allyloxy)propenes which are useful as fragrance or flavor ingredients in particular in providing green, fruity, pear and/or waxy olfactory notes. The present invention also relates to novel perfume, aroma or deodorizing/masking compositions comprising said odorants.

Tandem-directed regioselective hydroformylation/β-elimination: A practical method for the synthesis of enals

A practical synthesis of α,β-unsaturated aldehydes by a tandem-directed hydroformylation/β-elimination process of allylic o-DPPB esters is reported. The o-DPPB group served as an effective controller for regioselectivity of the hydroformylation towards th