224192-16-9Relevant academic research and scientific papers
Photo-assisted preparation of double isocyanide insertion complexes of η5-cyclopentadienyliron(II) bearing only isocyanide: The molecular structure of (η5-C5H5)Fe(XylNC) 2[C(=NXyl)C(=NXyl)CH3 (XylNC=2,6-Me2C6H3NC)
Yamamoto, Yasuhiro,Tsuji, Masayuki,Igoshi, Toshiaki
, p. 233 - 236 (2008/10/08)
Reaction of η5-C5H5Fe(CO)2CH3 (1) with xylyl isocyanide in toluene at reflux gave η5-C5H5Fe(CO)(XylNC)COCH3 (5a) (Xyl=2,6-(CH3)2C6H3), whereas photochemical reaction underwent double insertion of isocyanide molecules into an iron-carbon bond to give a bis-imino type complex (η5-C5H5)Fe(XylNC) 2[C(=NXyl)C(=NXyl)CH3] (6a), determined by an X-ray analysis.
