224325-89-7Relevant academic research and scientific papers
Biomimetic modeling of the abstraction of H3' by ribonucleotide reductases. 1,5-Hydrogen atom transfer of H3 to aminyl and oxyl, but not thlyl, free radicals in homoribofuranose derivatives
Guo, Zhiqiang,Samano, Mirna C.,Krzykawski, Jan W.,Wnuk, Stanislaw F.,Ewing, Gregory J.,Robins, Morris J.
, p. 5705 - 5718 (2007/10/03)
Generation of 6-oxyl radicals from homoribofuranose (5-deoxy-D-ribo- hexofuranose) 6-O-nitre esters with Bu3SnD/AIBN/benzene/Δ resulted in abstraction of H3 by a [1,5]-hydrogen atom shift. Transfer of 2H from the stannane to · C3 eff
