22441-13-0 Usage
Description
(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)LITHIUM is a chemical compound that serves as a versatile reactant in the synthesis of various organic and inorganic complexes. It is characterized by its unique structure, which includes a lithium atom coordinated to a 3,5-heptanedionate ligand with two methyl groups on each of the 2,2,6,6 positions. (2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)LITHIUM is known for its reactivity and ability to form stable complexes with a wide range of metal ions.
Uses
Used in Organic Synthesis:
(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)LITHIUM is used as a reactant for the synthesis of various organic complexes, such as bis-cycloiridiated complexes, cationic imido alkylidene complexes, and polyaromatic ligands containing pyrene. Its reactivity and ability to form stable complexes make it a valuable component in the development of new organic compounds with potential applications in various fields.
Used in Inorganic Synthesis:
In the field of inorganic chemistry, (2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)LITHIUM is used as a reactant for the synthesis of mono-cyclometalated platinum complexes. These complexes have potential applications in various areas, such as catalysis, materials science, and medicinal chemistry, due to their unique properties and reactivity.
Used in Electroluminescent Studies:
(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)LITHIUM is also used as a reactant for the synthesis of bis-cycloiridiated complexes, which are employed in electroluminescent studies. These studies are crucial for the development of new materials and devices with potential applications in lighting, displays, and other optoelectronic technologies.
Check Digit Verification of cas no
The CAS Registry Mumber 22441-13-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,2,4,4 and 1 respectively; the second part has 2 digits, 1 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 22441-13:
(7*2)+(6*2)+(5*4)+(4*4)+(3*1)+(2*1)+(1*3)=70
70 % 10 = 0
So 22441-13-0 is a valid CAS Registry Number.
22441-13-0Relevant articles and documents
Volatile single-source molecular precursor for the lithium ion battery cathode
Navulla, Anantharamulu,Huynh, Lan,Wei, Zheng,Filatov, Alexander S.,Dikarev, Evgeny V.
, p. 5762 - 5765 (2012)
The first single-source molecular precursor for a lithium-manganese cathode material is reported. Heterometallic β-diketonate LiMn2(thd) 5 (1, thd = 2,2,6,6-tetramethyl-3,5-heptanedionate) was obtained in high yield by simple one-step solid-state reactions employing commercially available reagents. Substantial scale-up preparation of 1 was achieved using a solution approach. The crystal structure of the precursor contains discrete Li:Mn = 1:2 trinuclear molecules held together by bridging diketonate ligands. The complex is relatively stable in open air, highly volatile, and soluble in all common solvents. It was confirmed to retain its heterometallic structure in solutions of non-coordinating solvents. The heterometallic diketonate 1 was shown to exhibit clean, low-temperature decomposition in air/oxygen that results in nanosized particles of spinel-type oxide LiMn2O4, one of the leading cathode materials for lithium ion batteries.
