224442-22-2Relevant academic research and scientific papers
1,9-Stereocontrol from 1,7-induction using an allylstannane followed by an Ireland-Claisen rearrangement
Moffatt, Ella-Maria,Thomas, Eric J.
, p. 3723 - 3734 (2007/10/03)
The 6-hydroxynona-2,7-dienylstananne 10 reacts with aldehydes after transmetallation with tin(IV) bromide with syn-selective 1,7-induction (1,7- syn : 1,7-anti = ca. 90 : 10). Ireland-Claisen rearrangements of the acetates 28a,b prepared from the syn-benz
