22452-76-2Relevant academic research and scientific papers
Gram-Scale Synthesis and Supramolecular Complex of Precursors of Clar's Hydrocarbon Triangulene
Ribar, Peter,?olomek, Tomá?,Jurí?ek, Michal
, p. 7124 - 7128 (2019)
We present to date the most efficient gram-scale synthesis of triangulene-4,8-dione and 12-hydroxytriangulene-4,8-dione, the precursors of Clar's hydrocarbon, in overall yields >50%. The direct dihydroprecursors of triangulene, obtained upon reduction of
Synthesis of a Derivative of Triangulene; the First Non-Kekule Polynuclear Aromatic
Allinson, Graeme,Bushby, Richard J.,Paillaud, Jean-Louis,Thornton-Pett, Mark
, p. 385 - 390 (2007/10/02)
The first synthesis of a non-Kekule polynuclear aromatic, a trioxy derivative of triangulene, has been achieved through a two-electron reduction of tetrabutylammonium 4,8-dioxo-4H,8H-dibenzopyren-12-olate 14.The single crystal X-ray diffraction str
