22481-06-7

Basic information

• Product Name: 1,2-Benzenedicarboxylic acid, 3-hydroxy-6-methyl-, dimethyl ester
• CAS NO: 22481-06-7
• Molecular Formula: C11H12O5
• Molecular Weight: 224.213
• Mol File: 22481-06-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,2-Benzenedicarboxylic acid, 3-hydroxy-6-methyl-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Benzenedicarboxylic acid, 3-hydroxy-6-methyl-, dimethyl ester(22481-06-7)
• EPA Substance Registry System: 1,2-Benzenedicarboxylic acid, 3-hydroxy-6-methyl-, dimethyl ester(22481-06-7)

Safety Data

• Hazardous Substances Data: 22481-06-7(Hazardous Substances Data)

Upstream product

• 18064-04-5 dimethyl 1-methyl-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate 
• 534-22-5 2-methylfuran 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 131236-62-9 3-Methyl-6-oxo-cyclohexa-1,4-diene-1,3-dicarboxylic acid dimethyl ester 
• 18064-04-5 dimethyl (1RS,4SR)-1-methyl-7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate 

Relevant articles and documents

METHOD TO PREPARE PHENOLICS FROM BIOMASS

The present invention is directed to a method for preparing a final phenolic product from biomass comprising the steps of providing a furanic compound obtainable from biomass; reacting the furanic compound with a dienophile to obtain a phenolic compound; reacting the phenolic compound further to obtain the final phenolic product.

Rhodium-catalyzed asymmetric cyclodimerization of oxabenzonorbornadienes and azabenzonorbornadienes: Scope and limitations

(Chemical Equation Presented) Cationic rhodium(I)-catalyzed cyclodimerization of oxabenzonorbornadienes produced naphtho[1,2-b]-furan ring systems in a single step with excellent yields and excellent enantioselectivities. The effect of various Rh(I) catalysts, Ag(I) salts, solvents, and phosphine ligands on the yield and enantioselectivity of the reaction was investigated, and the scope and limitations of this reaction with various oxabicyclic alkenes were studied. Similar results were obtained with the azabenzonorbornadiene analogues, providing the corresponding cyclodimerization products in excellent yields and excellent enantioselectivities.