22499-73-6Relevant academic research and scientific papers
A Contribution to the Photochemistry of the Singlet Excited 5-Methylenecyclohexa-1,3-diene System
Brune, Hans Albert,Guenther, Uwe,Lach, Peter,Sihler, Rolf
, p. 833 - 838 (2007/10/02)
1,2,3,4,6-Pentamethyl-5-methylenecyclohexa-1,3-diene and 1,2,3,4,6,6-Hexamethyl-5-methylenecyclohexa-1,3-diene have been synthesized.The isomerizations following singlet excitation have been studied. - Keywords: 5-Methylenecyclohexa-1,3-diene System, S1 Excitation, Isomerizations
A Contribution to the Mechanism of Light-induced Isomerizations of the 4-Methylenebicyclohex-2-ene
Brune, Hans Albert,Jobst, Helmuth,Lach, Peter
, p. 511 - 519 (2007/10/02)
Deuterium-labelling of 1,2,3,5,6-exo-pentamethyl-4-methylenebicyclohex-2-ene (exo-1) and 1,2,3,5,6-endo-pentamethyl-4-methylenebicyclohex-2-ene (endo-1) was used to get insight into the mechanisms of the reversible photo-isomerization exo-1 endo-1 and of their light-induced rearrangements to 1,2,3,4,6-pentamethyl-5-methylene-1,3-cyclohexadiene (2).
