225656-31-5

Basic information

• Product Name: methyl (R)-2-(9-fluorenylmethoxycarbonyl)amino-4-pentenoate
• Synonyms: methyl (R)-2-(9-fluorenylmethoxycarbonyl)amino-4-pentenoate
• CAS NO: 225656-31-5
• Molecular Weight: 351.402
• Mol File: 225656-31-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (R)-2-(9-fluorenylmethoxycarbonyl)amino-4-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (R)-2-(9-fluorenylmethoxycarbonyl)amino-4-pentenoate(225656-31-5)
• EPA Substance Registry System: methyl (R)-2-(9-fluorenylmethoxycarbonyl)amino-4-pentenoate(225656-31-5)

Safety Data

• Hazardous Substances Data: 225656-31-5(Hazardous Substances Data)

Upstream product

• 54594-06-8 D-allylglycine 

Relevant articles and documents

Synthesis of enantiopure functionalized pipecolic acids via amino acid derived N-acyliminium ions

The synthesis and enzymatic resolution of a novel vinylsilane-containing amino acid is described. Derivatization of this and other olefinic amino acids followed by subjection to standard N-acyliminium ion cyclization conditions provides the corresponding pipecolic acid derivatives with - in most cases - complete conservation of enantiopurity. In addition to studying the scope of this reaction, details of the N-acyliminium ion cyclization including an aza Cope equilibrium are highlighted.