225662-87-3Relevant academic research and scientific papers
An easy route to seven-membered iminocyclitols from aldohexopyranosyl enamines
Fuentes, Jose,Gasch, Consolacion,Olano, David,Pradera,Repetto, Guillermo,Sayago, Francisco J.
, p. 1743 - 1753 (2007/10/03)
A new stereocontrolled and high yielding synthesis of biologically active polyhydroxyperhydroazepines is reported starting from easily available glycosylenamines (D-gluco, D-manno, and D-galacto configurations), which are transformed into 1,6-azaanhydropy
Efficient synthesis of seven-membered iminocyclitols from glycosylenamines
Fuentes, Jose,Olano, David,Pradera, M. Angeles
, p. 4063 - 4066 (2007/10/03)
Seven membered iminocyclitols are synthesized in four steps from easily available glycosylenamines (D-gluco, D-galacto, and D-manno configurations) through 1,6-aza-anhydrosugar derivatives. These intermediates are transformed into 2-hydroxy- and 2-unsubstituted azepanes depending on the reactants used for the cleavage of the Cl-O bond. The overall yields are high.
