22575-37-7Relevant academic research and scientific papers
Water-Accelerated Claisen Rearrangements
Wipf, Peter,Rodriguez, Sonia
, p. 434 - 440 (2007/10/03)
Allyl aryl ethers undergo accelerated Claisen and [1,3] rearrangements in the presence of a mixture of trialkylalanes and water or aluminoxanes. The ratio of ortho-, meta-, and pora-Claisen products depends to a large extent on the presence of water and to a much lesser extent on the nature of the alane.
