225789-83-3

Basic information

• Product Name: W(CO)2Cl(dppe)(CC₆H₄(C_.tplbond.CC₆H₄NHCHO-4)-4)
• CAS NO: 225789-83-3
• Molecular Weight: 906.009
• Mol File: 225789-83-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: W(CO)2Cl(dppe)(CC₆H₄(C_.tplbond.CC₆H₄NHCHO-4)-4)(CAS DataBase Reference)
• NIST Chemistry Reference: W(CO)2Cl(dppe)(CC₆H₄(C_.tplbond.CC₆H₄NHCHO-4)-4)(225789-83-3)
• EPA Substance Registry System: W(CO)2Cl(dppe)(CC₆H₄(C_.tplbond.CC₆H₄NHCHO-4)-4)(225789-83-3)

Safety Data

• Hazardous Substances Data: 225789-83-3(Hazardous Substances Data)

Upstream product

• 225789-82-2 W(CO)2Cl(dppe)(CC₆H₄(C_.tplbond.CC₆H₄NH₂-4)-4) 
• 2258-42-6 formyl acetic anhydride 

Downstream Products

• 222301-96-4 W(CO)2Cl(dppe)(CC₆H₄(C_.tplbond.CC₆H₄NC-4)-4) 

Relevant articles and documents

Unsaturated alkylidyne ligands bearing a terminal isocyanide functionality and intervening ethynylbenzene groups

The synthesis of complexes 2 [W(CC6H4(CCC6H4NH 2-4)-4)Cl(CO)2(dppe)], and 4 [W(CC6H4(CCC6H4(CCC 6H2iPr2-3,5-NHCHO-4)-4)-4)Cl(CO) 2(dppe)], was achieved by Pd(II) catalyzed cross-coupling reactions of complex 1 [W(CC6H4I-4)Cl(CO)2(dppe)], with the respective aromatic acetylenes. Formylation of complex 2 with acetic formic anhydride affords the formamide 3 [W(CC6H4(CCC6H 4NHCHO-4)-4)Cl(CO)2(dppe)]. The isocyanide derivatives 5 [W(CC6H4(CCC6H4NC-4)-4)Cl(CO) 2(dppe)], and 6 [W(CC6H4(CCC6H4(CCC 6H2iPr2-3,5-NC-4)-4)-4)Cl(CO) 2(dppe)], were obtained by dehydration of complexes 3 and 4 with triphosgene/NEt3.