225797-86-4

Upstream product

• 225797-84-2 5,5'-Bis-(3-bromo-5-hexyloxymethylphenyl)-2,2'-bipyridyl 
• 15862-18-7 5,5'-dibromo-2,2'-dipyridyl 
• 276670-17-8 2-(3-Hexyloxymethyl-5-trimethylsilanylphenyl)-4,4,5,5-tetramethyl-[1,3,2]-dioxaborolane 
• 851605-33-9 2-bromo-5-[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-pyridine 
• 225932-22-9 2-Bromo-5-(3-bromo-5-hexyloxymethylphenyl)pyridine 
• 73290-22-9 2-bromo-5-iodo-pyridine 
• 624-28-2 2,5-dibromopyridine 
• 851605-32-8 5,5'-bis[3-hexyloxymethyl-5-(trimethylsilanyl)phenyl]-2,2'-bipyridinyl 

Downstream Products

• 869885-39-2 5,5'-bis-(3-(hexyloxymethyl)-5-(trimethylsilanylethynyl)phenyl)-[2,2']-bipyridyl 
• 945867-16-3 C₈₆H₁₁₂N₂O₆Si₂ 
• 945867-17-4 C₆₁H₇₇IN₂O₄Si 
• 851605-34-0 5,5'-bis(3-hexyloxymethyl-5-{3-hexyloxymethyl-5-[(triisopropylsilanyl)ethynyl]phenylethynyl}phenyl)-2,2'-bipyridinyl 
• 851605-41-9 5,5'-bis{3-hexyloxymethyl-5-[(3-iodophenyl)ethynyl]phenyl}-2,2'-bipyridinyl 
• 851605-40-8 5,5'-bis-(3-ethynyl-5-(hexyloxymethyl)phenyl)-[2,2']-bipyridyl 
• 851605-36-2 5,5'-bis{3-[3-ethynyl-5-(hexyloxymethyl)phenylethynyl]-5-(hexyloxymethyl)phenyl}-2,2'-bipyridinyl 
• 945867-23-2 C₅₂H₅₇IN₂O₄ 
• 945867-22-1 C₆₈H₇₂N₂O₆ 

Relevant academic research and scientific papers

A set of homologous hetarylenediyne macrocycles by oxidative acetylene-acetylene coupling

(Chemical Equation Presented) The synthesis of a set of bipyridine-containing macrocycles by oxidative acetylene-acetylene dimerization is described. The cycles are separated by preparative GPC, and the smallest homologue is analyzed by single-crystal X-ray diffraction, which shows a layered structure with channels that are partially filled with parts of the flexible chains of adjacent macrocycles. The cyclic trimer has a D3h symmetry and is a possible candidate for the formation of metal organic supramolecular assemblies on surfaces.

Shape-persistent macrocycles: A synthetic strategy that combines easy and site-specific decorations with improved cyclization efficiency

A flexible route to shape-persistent macrocycles based on a collection of building blocks has been devised that allows the easy introduction of several different functional units at predetermined positions and the obtainment of cycles as analytically pure

Shape-persistent macrocycles with bipyridine units: Progress in accessibility and widening of applicability

Several new symmetrical and nonsymmetrical bipyridine-containing building blocks for shape-persistent macrocycles were developed, whereby much emphasis was placed on especially efficient procedures. The building blocks were used for the synthesis of sever

Synthesis and an X-ray structure of soluble phenylacetylene macrocycles with two opposing bipyridine donor sites

The synthesis of the shape-persistent macrocycles 10a and 10b with two bipyridine units in opposing sides by Hagihara/Sonogashira cross-coupling chemistry of suitably functionalized building blocks is reported. X-ray analysis of single crystals of 10b sho