225915-82-2Relevant articles and documents
Laser flash photolysis of 3-noradamantyl(phenyl)diazomethane: Generation, detection and kinetics of 2-phenyladamantene
Hirai, Katsuyuki,Tomioka, Hideo,Okazaki, Takao,Tokunaga, Kazuhiko,Kitagawa, Toshikazu,Takeuchi, KeN'Ichi
, p. 165 - 169 (2007/10/03)
Laser flash photolysis of 3-noradamantyl(phenyl)diazomethane in degassed benzene at room temperature generates 2-phenyladamantene, which decays with second-order kinetics (2k/εl = 1.5 × 102 s-1) to give a dimer and is shown to react with oxygen and tri(n-butyl)tin hydride much faster than with methanol, thus revealing profound radical character of the twisted double bond. Copyright