225932-10-5Relevant articles and documents
Suzuki polycondensation toward high molecular weight poly(m -phenylene)s: Mechanistic insights and end-functionalization
Hohl, Benjamin,Bertschi, Louis,Zhang, Xiangyang,Schlueter, A. Dieter,Sakamoto, Junji
scheme or table, p. 5418 - 5426 (2012/09/05)
Synthesis of a poly(m-phenylene) by Suzuki polycondensation (SPC) using an AB-type m-phenylene monomer is reported (A and B refer to bromo and boron functional groups, respectively). Despite the attempted high molecular weight products, SPC under the conv
Synthesis of 5,5'-disubstituted 2,2'-bipyridines for modular chemistry
Henze, Oliver,Lehmann, Uwe,Schlüter, A. Dieter
, p. 683 - 687 (2007/10/03)
A 0.5-11 g scale synthesis of the 5,5'-disubstituted 2,2'-bipyridines 8 is described. The pyridine units are connected to one another by Pd-catalyzed cross-coupling reactions. This method allows one to introduce bromo functions and flexible chains at the