22594-23-6

Basic information

• Product Name: Gulonicacid,3,6-anhydro-,gamma-lactone,L-(8CI)
• Synonyms: Gulonicacid,3,6-anhydro-,gamma-lactone,L-(8CI)
• CAS NO: 22594-23-6
• Molecular Formula: C6H8O5
• Molecular Weight: 160.12472
• Product Categories: CARBOHYDRATE
• Mol File: 22594-23-6.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Gulonicacid,3,6-anhydro-,gamma-lactone,L-(8CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Gulonicacid,3,6-anhydro-,gamma-lactone,L-(8CI)(22594-23-6)
• EPA Substance Registry System: Gulonicacid,3,6-anhydro-,gamma-lactone,L-(8CI)(22594-23-6)

Safety Data

• Hazardous Substances Data: 22594-23-6(Hazardous Substances Data)

Upstream product

• 54060-56-9 3.6-anhydro-d-gluconic acid 
• 87638-77-5 Methyl-3,6-anhydro-β-D-glucofuranosid 
• 3056-46-0 methyl 3,6-anhydro-β-D-glucopyranoside 
• 1128-23-0 L-gulono-1,4-lactone 
• 6322-07-2 D-gulono-1,4-lactone 
• 161168-87-2 D-idono-1,4-lactone 
• 161085-46-7 6-bromo-6-deoxy-D-idono-1,4-lactone 
• 90-80-2 D-Glucono-1,5-lactone 
• 7625-23-2 3,6-anhydro-D-glucose 
• 26301-79-1 D-mannono-1,4-lactone 
• 161085-43-4 6-bromo-6-deoxy-D-mannono-1,4-lactone 

Relevant articles and documents

Synthesis of 6-amino-6-deoxy-d-gulono-1,6-lactam and l-gulono-1,6-lactam derived from corresponding 5,6-O-sulfinyl hexono-1,4-lactones

Syntheses of 6-amino-6-deoxy-2,3-O-isopropylidene-d-gulono- and l-gulono-1,6-lactams 3 and 4 from corresponding glycono-1,4-lactones are described. Activation of the primary hydroxyl group requires 5,6-cyclic sulfite intermediate to obtain 6-azido-6-deoxy

Enantiomerically Pure, Highly Functionalized Tetrahydrofurans from Simple Carbohydrate Precursors

6-Bromo-6-deoxy-1,4-aldonolactones and 6-bromo-6-deoxy-alditols with D-galacto, D-altro-, D-manno- and D-ido-configuration were selectively converted into hydroxylated tetrahydrofuran derivatives by simple heating in water.The 6-bromo-6-deoxy-altritol (10) and 6-bromo-6-deoxy-D-iditol (25) reacted even at room temperature.Likewise, 6-bromo-2,6-dideoxy-aldonolactones with D-arabino- (29) and D-lyxo-configuration (31) gave the corresponding 2-deoxy-3,6-anhydride, when heated in water.The rate of formation of the furan ring by intramolecular nucleophilic substitution was determined by the conformation of the bromopolyols in water.