226-59-5Relevant articles and documents
Oxidative coupling of diaryldisulfides by MoCl5 to thianthrenes
Spurg, Anke,Schnakenburg, Gregor,Waldvogel, Siegfried R.
scheme or table, p. 13313-13317+13274 (2010/06/15)
"Chemical Equation Presented" Oxidative C-S coupling: The oxidative coupling reaction of 1,2-diaryldisulfides by using MoCl5 or mixtures thereof with TiCl4 gives fast and efficient access to dibenzo[b,e] [1,4]dithiins such as that depicted (thianthrenes).
Stacking Structure with Trimolecular Units of Donor-Acceptor-Donor in a Charge-transfer Complex of Dinaphtho-1,4-dithiin with Tetracyanoquinodimethane
Kobayashi, Keiji,Takahashi, Miyuki,Kobayashi, Hayao
, p. 427 - 430 (2007/10/02)
Dinaphtho-1,4-dithiin (DND) was prepared as an electron-donor species and upon reaction with the electron-acceptor species 7,7,8,8-tetracyanoquinodimethane (TCNQ) was found to form a charge-transfer complex with a donor:acceptor ratio of 2:1.The crystal and molecular structure of this complex has been determined.The molecules are arranged in a mixed stack composed of the trimolecular donor-acceptor-donor units, which are further linked by donor-donor overlap.The donor molecules are folded along the S-S axis with a dihedral angle of 140.6 deg.