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226387-11-7 Usage

General Description

The chemical compound (S)-2-(4,5-Dihydro-4-isopropyl-2-oxazolyl)quinoline, also known as (S)-DIPQ, is a heterocyclic compound featuring a quinoline ring and an isopropyl-oxazolyl moiety. It is a chiral compound, with the (S)-enantiomer being the active form. (S)-DIPQ has been studied for its potential use in medicinal chemistry, particularly as a catalyst in asymmetric synthesis. It has also shown promise as a fluorescent probe for detecting and imaging biological structures. Additionally, this compound has been investigated for its potential antioxidant and neuroprotective properties. Overall, (S)-2-(4,5-Dihydro-4-isopropyl-2-oxazolyl)quinoline has diverse potential applications in various fields of chemistry and biochemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 226387-11-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,2,6,3,8 and 7 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 226387-11:
(8*2)+(7*2)+(6*6)+(5*3)+(4*8)+(3*7)+(2*1)+(1*1)=137
137 % 10 = 7
So 226387-11-7 is a valid CAS Registry Number.

226387-11-7 Well-known Company Product Price

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  • Aldrich

  • (731005)  (S)-2-(4,5-Dihydro-4-isopropyl-2-oxazolyl)quinoline  97%

  • 226387-11-7

  • 731005-250MG

  • 595.53CNY

  • Detail
  • Aldrich

  • (731005)  (S)-2-(4,5-Dihydro-4-isopropyl-2-oxazolyl)quinoline  97%

  • 226387-11-7

  • 731005-1G

  • 2,084.94CNY

  • Detail

226387-11-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name (S)-2-(4,5-Dihydro-4-isopropyl-2-oxazolyl)quinoline

1.2 Other means of identification

Product number -
Other names (4S)-4-propan-2-yl-2-quinolin-2-yl-4,5-dihydro-1,3-oxazole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:226387-11-7 SDS

226387-11-7Downstream Products

226387-11-7Relevant articles and documents

Ligand-Controlled Regiodivergence in Nickel-Catalyzed Hydroarylation and Hydroalkenylation of Alkenyl Carboxylic Acids**

Deng, Ruohan,Engle, Keary M.,Fu, Yue,Gao, Yang,Li, Zi-Qi,Liu, Peng,Tran, Van T.

supporting information, p. 23306 - 23312 (2020/10/19)

A nickel-catalyzed regiodivergent hydroarylation and hydroalkenylation of unactivated alkenyl carboxylic acids is reported, whereby the ligand environment around the metal center dictates the regiochemical outcome. Markovnikov hydrofunctionalization products are obtained under mild ligand-free conditions, with up to 99 % yield and >20:1 selectivity. Alternatively, anti-Markovnikov products can be accessed with a novel 4,4-disubstituted Pyrox ligand in excellent yield and >20:1 selectivity. Both electronic and steric effects on the ligand contribute to the high yield and selectivity. Mechanistic studies suggest a change in the turnover-limiting and selectivity-determining step induced by the optimal ligand. DFT calculations reveal that in the anti-Markovnikov pathway, repulsion between the ligand and the alkyl group is minimized (by virtue of it being 1° versus 2°) in the rate- and regioselectivity-determining transmetalation transition state.

Efficacious and rapid metal- and solvent-free synthesis of enantiopure oxazolines

Hassani, Rym,Requet, Alexandre,Marque, Sylvain,Gaucher, Anne,Prim, Damien,Kacem, Yakdhane,Hassine, Bchir Ben

, p. 1275 - 1279 (2015/01/08)

A rapid and efficient synthesis of oxazolines was performed starting from various nitriles using microwave irradiation combined to metal- and solvent-free conditions to afford high to quantitative yields of the targeted heterocycles.

Palladium(II)-catalyzed enantioselective aerobic dialkoxylation of 2-propenyl phenols: A pronounced effect of copper additives on enantioselectivity

Zhang, Yang,Sigman, Matthew S.

, p. 3076 - 3077 (2008/04/18)

A direct O2-coupled Pd(II)-catalyzed enantioselective dialkoxylation of 2-propenylphenols has been developed by utilizing chiral quinoline oxazoline ligands. A detrimental effect of added copper salts on enantioselectivity was observed which is attributed to the displacement of the chiral ligand off of Pd(II). Copyright

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