22644-30-0Relevant academic research and scientific papers
Total synthesis of emericellamide A: A secondary metabolite of marine cyclic depsipeptide with antimicrobial properties
Ma, Jing-Yi,Xu, Long-Fei,Huang, Wen-Feng,Wei, Bang-Guo,Lin, Guo-Qiang
scheme or table, p. 1307 - 1310 (2009/11/30)
Emericellamide A is a secondary metabolite of marine cyclic depsipeptide from the co-culture of the marine-derived fungus Emericella sp. and actinomycete Salinispora arenicola. A general method for the total synthesis of emericellamide A is depicted in th
Enantioselective synthesis of α-alkyl-β,γ-unsaturated esters through efficient Cu-catalyzed allylic alkylations
Murphy, Kerry E.,Hoveyda, Amir H.
, p. 4690 - 4691 (2007/10/03)
Treatment of an (allyl)organosilane with silica gel in refluxing toluene brought about deallylation forming an Si-O-Si bond with the silicon on the silica gel. This Si-O-Si bond formation provides us with a new reliable method for the functionalization of a silica gel surface. Copyright
A NEW SYNTHESIS OF (4R,8R)-4,8-DIMETHYLDECANAL - THE PHEROMONE OF THE MEAL WORMS Tribolium confusum AND Tribolium castaneum
Hao, Nguyen Kong,Cheskis, B. A.,Mavrov, M. V.,Moiseenkov, A. M.,Serebryakov, E. P.
, p. 449 - 453 (2007/10/02)
A method of synthesis was developed for (4R,8R)-4,8-dimethyldecanal - the aggregation pheromone of the meal worms Tribolium confusum and T. castaneum.It contains altogether 12 stages and uses (R)-(+)-5-acetoxy-4-ethylpentanoic acid and (S)-(+)-3,7-dimethyl-1,6-octadiene as the initial chiral compounds.The overall yield of the pheromone amounted to 27percent on the initial acid or 15percent on the initial diene.The optical purity of the chiral centers C-4 and C-8 in the molecule of the pheromone was estimated as ca. 55 and ca. 97percent respectively.
