226570-65-6 Usage
Uses
Used in Chemical Synthesis:
4-PENTENYLZINC BROMIDE is used as a starting material for the synthesis of various organic compounds, particularly in the preparation of complex molecules with potential applications in different industries.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 4-PENTENYLZINC BROMIDE is used as a synthetic building block for the development of new drugs. Its reactivity allows for the creation of diverse molecular structures that can target specific biological pathways, potentially leading to the discovery of novel therapeutic agents.
Used in Material Science:
4-PENTENYLZINC BROMIDE can be utilized in the development of advanced materials with unique properties. Its incorporation into the synthesis of various compounds can result in materials with enhanced performance characteristics, such as improved stability, reactivity, or selectivity.
Used in the Synthesis of 3,6-bis[(cyclopentyl)methyl]phthalonitrile:
4-PENTENYLZINC BROMIDE is used as a key intermediate in the preparation of octasubstituted phthalocyanines, which are important compounds with a wide range of applications, including as pigments, dyes, and in the development of new materials with unique optical, electronic, and catalytic properties.
Check Digit Verification of cas no
The CAS Registry Mumber 226570-65-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,2,6,5,7 and 0 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 226570-65:
(8*2)+(7*2)+(6*6)+(5*5)+(4*7)+(3*0)+(2*6)+(1*5)=136
136 % 10 = 6
So 226570-65-6 is a valid CAS Registry Number.
InChI:InChI=1/C5H9.BrH.Zn/c1-3-5-4-2;;/h3H,1-2,4-5H2;1H;/q;;+1/p-1/rC5H9BrZn/c1-2-3-4-5-7-6/h2H,1,3-5H2
226570-65-6Relevant academic research and scientific papers
A general strategy for the synthesis of enantiomerically pure azetidines and aziridines through nickel-catalyzed cross-coupling
Jensen, Kim L.,Nielsen, Dennis U.,Jamison, Timothy F.
supporting information, p. 7379 - 7383 (2015/05/13)
Abstract In this communication, we report a straightforward synthesis of enantiomerically pure 2-alkyl azetidines. The protocol is based on a highly regioselective nickel-catalyzed cross-coupling of aliphatic organozinc reagents with an aziridine that fea
The reaction of active zinc with organic bromides
Guijarro, Albert,Rosenberg, David M.,Rieke, Reuben D.
, p. 4155 - 4167 (2007/10/03)
The oxidative addition of highly reactive zinc to organic bromides shows a pronounced structure-reactivity dependence, in contrast to that shown by other metals. The kinetic and LFER studies suggest a mechanism in which electron transfer (ET) is the rate-determining step of the reaction. Experiments carried out with radical clocks as well as the stereochemical outcome of the reaction support the presence of radicals. The reactivity profiles suggest that the ET has an important component of inner-sphere process in the reaction with alkyl bromides. In the case of aryl halides, Hammet plots are consistent with the participation of aryl halide radical anions as intermediates. The reaction contemplated here can be ascribed as another example of radical-mediated selective reaction, and it has straightforward synthetic applications. Some synthetic work was done in this direction, to demonstrate how this structure-reactivity dependence can be used to obtain selective organozinc formation in unsymmetrical dibromides.
