226985-54-2

Upstream product

• 58888-62-3 ethyl 6-O-tert-butyldimethylsilyl-4-hydroxyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 121898-42-8 (2-Bromocyclohex-1-enyl)methyl bromide 

Relevant academic research and scientific papers

Palladium-mediated cyclization on carbohydrate templates synthesis of enantiopure annelated tricyclic compounds

Various bromo unsaturated carbohydrates 2-4 have been prepared from ethyl and aryl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside by deacetylation, followed firstly by monosilylation with TBDMSCl and then by alkylation with 2-bromobenzyl brom

Intramolecular heck cyclisation-β-alkoxy elimination in carbohydrate chemistry. A simple route to to enantiopure annelated dioxatricyclic compounds

Enantiopure cis-fused pyrano[2,3]pyrans are obtained from glycals via an intramolecular Heck cyclization followed by a palladium-β=alkoxy elimination.