227-86-1

Usage

InChI:InChI=1/C16H10S/c1-2-4-13-10-15-14(9-12(13)3-1)6-5-11-7-8-17-16(11)15/h1-10H

Upstream product

• 855880-43-2 anthra[1,2-b]thiophene-4,5-dicarboxylic acid-anhydride 
• 80090-42-2 6,11-dihydro-6,11-dioxoanthra<1,2-b>thiophene 
• 14861-60-0 1-(thiophen-3-yl)ethan-1-ol 
• 130-15-4 [1,4]naphthoquinone 
• 80090-38-6 4,5,6,11-tetrahydro-6,11-dioxoanthra<1,2-b>thiophene 
• 1468-83-3 1-(thiophen-3-yl)-ethanone 
• 13679-64-6 3-vinylthiophene 
• 260997-55-5 2-carbomethoxy-4,5,7,8,9,10-hexahydroanthra[1,2-b]thiophene 
• 260997-56-6 4,5,7,8,9,10-hexahydroanthra[1,2-b]thiophene-2-carboxylic acid 
• 223264-21-9 1-chloro-3,4,6,7,8,9-hexahydroanthracene-2-aldehyde 
• 5440-71-1 3,4,5,6,7,8-hexahydro-1(2H)-anthracenone 
• 260997-57-7 4,5,7,8,9,10-hexahydroanthra[1,2-b]thiophene 

Relevant academic research and scientific papers

Studies on cavity shaped polycyclic thiaarenes: Short and efficient synthesis of 2,12-dimethylanthra[1,2-b][8,7-b]bisthiophene and anthra[1,2-b]thiophene

A short, efficient and high yielding synthesis of anthra[1,2-b][8,7-b]bisthiophene (5) and anthra[1,2-b]thiophene (12) is described. Compound 5 has been synthesised by condensation of methyl thioglycolate with the bis-chloroaldehyde 1 to give the 2,10-dicarbomethoxyanthra[1,2-b][8,7-b]bisthiophene (2). Subsequent hydrolysis of the diester followed by decarboxylation of the resulting diacid 3 produces 4,5,7,8-tetrahydroanthra[1,2-b][8,7-b]bisthiophene (4) which is aromatized with DDQ to furnish compound 5. Following the similar sequence of reaction on the chloroaldehyde 8 anthra[1,2-b]thiophene (12) has been synthesised. Compound 5 on further methylation with n-BuLi and MeI results in the formation of the dimethyl derivative 6.

Synthesis of Anthrathiophenes and Benzonaphthothiophenes

All isomers of the parent anthrathiophenes and benzonaphthothiophenes, namely anthrathiophene, anthrathiophene, anthrathiophene, benzonaphthothiophene, benzonaphthothiophene and benzonaphthothiophene were synthesized using a new procedure.