227005-29-0

Upstream product

• 227005-28-9 CH₃C[CH₂P(C₆H₅)2]3IrH₂(C₈SH₈)⁽¹⁺⁾*B(C₆H₅)4^(1-)=CH₃C[CH₂P(C₆H₅)2]3IrH₂(C₈SH₈)B(C₆H₅)4 

Downstream Products

• 150266-23-2 IrH₂(CH₃C(CH₂P(C₆H₅)2)3)(SC₆H₄C₂H₅) 

Relevant academic research and scientific papers

First example of opening and hydrogenation of 2,3-dihydrobenzo[b]thiophene to 2-ethylthiophenol assisted by a soluble metal complex

Displacement of THF by dihydrobenzo[b]thiophene (DHBT) in [(triphos)Ir(H)2(THF)]BPh4 yields the η1-S-DHBT adduct [(triphos)Ir(H)2(η1-DHBT)]BPh4 which reacts in THF at room temperature with KOBu(t) to give the neutral 2-vinylthiophenolate derivative (triphos)Ir(H)2{η1-o-S(C6H4)CH=CH2} via C2-S bond cleavage; the latter compound is hydrogenated under mild conditions (2 bar H2, 80°C) to the 2-ethylthiophenolate derivative (triphos)Ir(H)2{o-S(C6H4)Et} and under harsh conditions (30 bar H2, 160°C) to free 2-ethylthiophenol and (triphos)IrH3.