22714-03-0

Basic information

• Product Name: 5,7-Dinitrobenzofurazan-4-ol
• Synonyms: 5,7-Dinitrobenzofurazan-4-ol
• CAS NO: 22714-03-0
• Molecular Formula: C6H2 N4 O6
• Molecular Weight: 0
• Mol File: 22714-03-0.mol

Chemical Properties

• Boiling Point: 236.4°C at 760 mmHg
• Flash Point: 96.8°C
• Appearance: /
• Density: 2.35g/cm³
• Vapor Pressure: 0.0475mmHg at 25°C
• Refractive Index: 1.9
• CAS DataBase Reference: 5,7-Dinitrobenzofurazan-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 5,7-Dinitrobenzofurazan-4-ol(22714-03-0)
• EPA Substance Registry System: 5,7-Dinitrobenzofurazan-4-ol(22714-03-0)

Safety Data

• Hazardous Substances Data: 22714-03-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H2N4O6/c11-6-3(10(14)15)1-2(9(12)13)4-5(6)8-16-7-4/h1,7H

Upstream product

• 118-02-5 2,4-dinitrosoresorcinol 
• 874-06-6 4-hydroxybenzofurazan 
• 68579-76-0 7-chloro-4,6-dinitro-benzofurazan 
• 79263-46-0 (5,7-Dinitro-benzo[1,2,5]oxadiazol-4-yl)-diethyl-amine 
• 70264-71-0 4,6-dinitro-2,1,3-benzoxadiazole 

Relevant articles and documents

Highly Electrophilic Heteroaromatics: the Hydrolysis of 7-Chloro-4,6-dinitrobenzofurazan and 7-Chloro-4,6-dinitrobenzofuroxan in Aqueous Solution

The hydrolysis of 7-chloro-4,6-dinitrobenzofurazan (4) and 7-chloro-4,6-dinitrobenzofuroxan (5) to give the related 7-hydroxy derivatives has been kinetically investigated in the pH range 1-6 in aqueous solution.The reactions occur 3500 and 10000 times more rapidly, respectively, than the hydrilysis of picryl chloride, emphasizing the much higher electrophilic character of the two heterocycles.Strong catalysis of the hydrolysis of 4 and 5 by carboxylate ions is observed, with Broensted β values of 0.38 and 0.42, respectively, which support a concerted mechanism.Although the corresponding points (kH2O/55.55) show strong negative deviations from the Broensted plots, the finding of appreciable solvent isotope effects (kH2O/kD2O ca. 1.75) favours a similar mechanism for the water reactions, i.e. water attack is assisted by a second water molecule which acts as a base catalyst.Differences in the electrostatic effects contributing to the stabilization of the transition ststes for the water-catalysed and carboxylate ion-catalysed reactions would account for the deviations observed for the kH2O points.