22735-96-2

Basic information

• Product Name: ethylene bis(cyclohexanecarboxylate)
• Synonyms: ethylene bis(cyclohexanecarboxylate);Di(cyclohexanecarboxylic acid)1,2-ethanediyl ester;Einecs 245-185-0
• CAS NO: 22735-96-2
• Molecular Formula: C₁₆H₂₆O₄
• Molecular Weight: 282.37524
• EINECS: 245-185-0
• Mol File: 22735-96-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 382.6°Cat760mmHg
• Flash Point: 184.9°C
• Appearance: /
• Density: 1.087g/cm³
• Vapor Pressure: 4.68E-06mmHg at 25°C
• Refractive Index: 1.491
• CAS DataBase Reference: ethylene bis(cyclohexanecarboxylate)(CAS DataBase Reference)
• NIST Chemistry Reference: ethylene bis(cyclohexanecarboxylate)(22735-96-2)
• EPA Substance Registry System: ethylene bis(cyclohexanecarboxylate)(22735-96-2)

Safety Data

• Hazardous Substances Data: 22735-96-2(Hazardous Substances Data)

Usage

Uses

Dicyclohexanecarboxylate Ethylene Glycol is used to study traction fluids.

InChI:InChI=1/C16H26O4/c17-15(13-7-3-1-4-8-13)19-11-12-20-16(18)14-9-5-2-6-10-14/h13-14H,1-12H2

Upstream product

• 110-82-7 cyclohexane 
• 201230-82-2 carbon monoxide 
• 107-21-1 ethylene glycol 

Relevant articles and documents

Oxidative Alkane C?H Alkoxycarbonylation

Directly utilizing a chemical feedstock to construct valuable compounds is an attractive prospect in organic synthesis. In particular, the combination of C(sp3)?H activation and oxidative carbonylation involving alkanes and CO gas is a promising and efficient method to synthesize carbonyl derivatives. However, due to the high C?H bond dissociation energy and low polarity of unactivated alkanes, the carbonylation of unactivated C(sp3)?H bonds still remains a great challenge. In this work, we introduce a palladium-catalyzed radical oxidative alkoxycarbonylation of alkanes to prepare numerous alkyl carboxylates. Various alkanes and alcohols were compatible, generating the desired products in up to 94 % yield. Remarkably, ethane, a constituent of natural gas, could be employed as a substrate under the standard reaction conditions. Preliminary mechanistic studies revealed a probable palladium-catalyzed radical process.