227466-03-7

Basic information

• Product Name: (E)-4-<(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)sulfanyl>-5-methyl-1-phenylhex-1-en-3-one
• Synonyms: (E)-4-<(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)sulfanyl>-5-methyl-1-phenylhex-1-en-3-one
• CAS NO: 227466-03-7
• Molecular Weight: 368.434
• Mol File: 227466-03-7.mol

Chemical Properties

• CAS DataBase Reference: (E)-4-<(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)sulfanyl>-5-methyl-1-phenylhex-1-en-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-<(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)sulfanyl>-5-methyl-1-phenylhex-1-en-3-one(227466-03-7)
• EPA Substance Registry System: (E)-4-<(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)sulfanyl>-5-methyl-1-phenylhex-1-en-3-one(227466-03-7)

Safety Data

• Hazardous Substances Data: 227466-03-7(Hazardous Substances Data)

Upstream product

• 58293-36-0 5,5-dimethyl-2-oxo-2-chlorosulfenyl-1,3,2-dioxaphosphorinane 
• 2892-18-4 (E)-5-methyl-1-phenylhex-1-en-3-one 

Downstream Products

• 17697-67-5 5-methyl-1-phenyl-(E,Z)-1,3-hexadiene 
• 873653-98-6 3,4-epithio-5-methyl-1-phenyl-(E)-1-hexene 
• 134259-48-6 (Z)-4-Methyl-2-((E)-styryl)-pent-2-enenitrile 

Relevant articles and documents

A general synthesis of thiophosphates containing an α,β-unsaturated carbonyl moiety

The O-silylated dienolates of α,β-unsaturated ketones and aldehydes can be thiophosphorylated using O,O-dialkyl chlorothiophosphonates and O,O- dialkyl bromodithiophosphonates to give a new class of compounds thio- and dithiophosphates 1-4 in high yield.

A general one-pot synthesis of vinyl-thiiranes and conjugated dienes

The first general synthesis of vinyl-thiiranes 7 and an effiecient preparation of conjugated dienes 8 and 9 is presented. Methodology described for the preparation of these compounds is based on the corresponding readily available thiophosphates 1 and selenophosphates 2.

A general one-pot synthesis of vinyl-thiiranes and conjugated dienes

The first general synthesis of vinyl-thiiranes 5 and an efficient preparation of conjugated dienes 6 and 7 based on thio, and selenophosphates is described.