227952-63-8

Basic information

• Product Name: (S)-diethyl (phenylsulfinyl)methylphosphonate
• Synonyms: (S)-diethyl (phenylsulfinyl)methylphosphonate
• CAS NO: 227952-63-8
• Molecular Weight: 276.293
• Mol File: 227952-63-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-diethyl (phenylsulfinyl)methylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-diethyl (phenylsulfinyl)methylphosphonate(227952-63-8)
• EPA Substance Registry System: (S)-diethyl (phenylsulfinyl)methylphosphonate(227952-63-8)

Safety Data

• Hazardous Substances Data: 227952-63-8(Hazardous Substances Data)

Upstream product

• 100-68-5 methyl-phenyl-thioether 
• 7205-91-6 phenylthiomethyl chloride 
• 38066-16-9 diethyl [(phenylthio)methyl]phosphonate 

Downstream Products

• 1258867-96-7 (R,E)-3-(tert-butyl(dimethyl)silyl)oxy-prop-1-enyl-phenylsulfoxide 
• 1193-82-4 (S)-methylphenylsulfoxide 
• 16491-20-6 (R)-1-methyl-4-(phenylsulfinyl)benzene 

Relevant articles and documents

An elimination approach to the synthesis of (+)-Scorodonin

1,2-Elimination of optically-active vinyl sulfoxide-allylic acetates led to corresponding allenynes in excellent yields. When the chirality of the sulfinyl group "matched" that at the allylic position, the chirality at the allylic stereogenic center could be efficiently transferred to the allenic axis.