22819-90-5Relevant academic research and scientific papers
MECHANISMS OF FREE-RADICAL REACTIONS. XIV. SELECTIVITY OF FREE-RADICAL CHLORINATION OF VALERIC ACID DERIVATIVES WITH ARYLCHLOROIODONIUM CHLORIDES
Dneprovskii, A. S.,Krainyuchenko, I. V.
, p. 324 - 328 (2007/10/02)
The free-radical chlorination of C4H9Y compounds with arylchloroiodonium chlorides was investigated.The reaction of the secondary C-H bonds increases as they become further from the electronegative substituent.The reaction parameters were calculated from the ratio of the β- and γ-monochlorides by means of the Taft equation.The absolute value of ρ increases with the introduction of electronwithdrawing substituents into the arylchloroiodonium chloride molecule.
Free Radical Substitution. Part 37. The Effect of Solvent on the Atomic Chlorination of 1-Substituted Butanes and Related Compounds
Potter, Alan,Tedder, John M.
, p. 1689 - 1692 (2007/10/02)
Experimental results reported in this paper show that the relative selectivity of atomic chlorination of 1-substituted butanes and related compounds is greatly influenced by the phase and by solvents.Solvents can be divided into three classes: (a) inert, (b) solvents which decrease the selectivity, and (c) solvents which increase the selectivity.The second group solvate the transition state and the third group solvate the chlorine atoms.
