228417-22-9Relevant academic research and scientific papers
Metal-catalyzed oxidation and epoxidation of α-hydroxy vinyl and dienyl sulfoxides
De La Pradilla, Roberta Fernandez,Castellanos, Alejandro,Fernandez, Jorge,Lorenzo, Milagros,Manzano, Pilar,Mendez, Paloma,Priego, Julian,Viso, Aima
, p. 1569 - 1575 (2007/10/03)
Treatment of acyclic α-hydroxyalkyl α,β-unsaturated sulfoxides with t-BuOOH/VO(acac)2 results in rapid oxidation to the unsaturated sulfones followed by an unusual regio- and stereoselective epoxidation at the unsaturated sulfones; this methodo
Highly stereoselective metal-catalyzed epoxidation of hydroxy vinyl sulfones
Fernandez De La Pradilla, Roberto,Mendez, Paloma,Priego, Julian,Viso, Alma
, p. 1247 - 1249 (2007/10/03)
Acyclic α-hydroxyalkyl α,β-unsaturated sulfoxides undergo oxidation at sulfur followed by a highly regio- and stereoselective epoxidation at the electron deficient alkene by treatment with ButOOH-VO(acac)2; this methodology allows fo
