228549-67-5

Upstream product

• 297747-81-0 (2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5R)-3,4-bis-benzyloxy-2-benzyloxymethoxymethyl-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yloxy]-tetrahydro-pyran-2-carboxylic acid 
• 228549-28-8 2,3,3',4,4'-penta-O-benzyl-1'-O-benzyloxymethyl-6'-O-t-butyldiphenylsilylsucrose 
• 297747-79-6 (2S,3S,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-[(2S,3S,4R,5R)-3,4-bis-benzyloxy-2-benzyloxymethoxymethyl-5-(tert-butyl-diphenyl-silanyloxymethyl)-tetrahydro-furan-2-yloxy]-tetrahydro-pyran-2-carbaldehyde 
• 128478-99-9 methylphosphonic acid dimethyl ester; deprotonated form 
• 228549-62-0 methyl (3,4-di-O-benzyl-1-O-benzyloxymethyl-6-O-t-butyldiphenylsilyl-β-D-fructofuranosyl)-(2<->1)-2,3,4-tri-O-benzyl-α-D-glucopyranosid)uronate 
• 756-79-6 dimethyl methane phosphonate 

Relevant academic research and scientific papers

Reaction of sugar phosphonates with sucrose aldehydes. Synthesis of higher analogs of sucrose

The Horner-Emmons reaction between sugar phosphonates Sug-C(O)CH2 P(O)(OMe)2 and aldehydes derived from sucrose afforded precursors of higher analogs of the general formula Sug-C(O)CH=CH-Suc. An example of the functionalization of th

Synthesis of sucrose derivatives modified at the terminal carbon atoms

The methodology for the preparation of various derivatives of sucrose modified at Cl′, C6, and C6′-positions is presented. 6-Amino-, 6′-amino-, and 6,6′-diamino-penta-O-benzylsucroses (16, 17 and 18 respectively), as well as appropriate uronic acids (characterized as methyl esters: 19-22), have been obtained from 2,3,4,3′4′-penta-O-benzylsucrose (1). The usefulness of this approach was exemplified by the preparation of 1′-O-benzyloxymethyl-6-deoxy-6-C-(2-furyl)-2,3,4,3′4′-penta-O- benzylsucrose (26).