22873-15-0

Basic information

• Product Name: Methylcarbamothioic acid S-(p-nitrophenyl) ester
• Synonyms: Methylcarbamothioic acid S-(p-nitrophenyl) ester
• CAS NO: 22873-15-0
• Molecular Formula: C₈H₈N₂O₃S
• Molecular Weight: 212.2257
• Mol File: 22873-15-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: 1.37g/cm³
• Refractive Index: 1.616
• CAS DataBase Reference: Methylcarbamothioic acid S-(p-nitrophenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methylcarbamothioic acid S-(p-nitrophenyl) ester(22873-15-0)
• EPA Substance Registry System: Methylcarbamothioic acid S-(p-nitrophenyl) ester(22873-15-0)

Safety Data

• Hazardous Substances Data: 22873-15-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C8H8N2O3S/c1-9-8(11)14-7-4-2-6(3-5-7)10(12)13/h2-5H,1H3,(H,9,11)

Upstream product

• 123-39-7 N-Methylformamide 
• 1150-28-3 S-(4-nitrophenyl) benzenesulfonothioate 
• 624-83-9 methyl isocyanate 
• 1849-36-1 para-nitrobenzenethiol 

Downstream Products

• 96408-98-9 N-(methyl)-N-nitrosocarbamate du nitro-4 thiophenol 

Relevant articles and documents

Visible-light-promoted synthesis of secondary and tertiary thiocarbamates from thiosulfonates andN-substituted formamides

A general visible-light-promoted metal-free synthesis of secondary and tertiary thiocarbamates starting from thiosulfonates andN-substituted formamides is developed. By employing rhodamine B as a photocatalyst andtert-butyl hydroperoxide (TBHP) as an oxidant, a wide scope of thiocarbamates can be obtained through direct thiolation of acyl C-H bonds under irradiation of blue light at room temperature for 12 h.

Methods for controlling fungi

Both novel and known S-(substituted-phenyl) N-alkylthiolcarbamates such as 4-fluorophenyl N-methylthiolcarbamate, and S-(substituted-phenyl) N,N-dialkylthiolcarbamates such as 2-chlorophenyl N,N-dimethylthiolcarbamate are disclosed. These are useful to control plant pests such as Phytophthorans infestans (Late Blight of Tomatoes) and Pythium ultimum (Damping Off). Also disclosed are the methods of controlling this plant pest with these compounds.