228850-12-2

Upstream product

• 228850-10-0 methyl 3-O-acetyl-4-O-benzoyl-6-bromo-2,6-dideoxy-2-fluoro-α-D-allopyranoside 
• 149057-38-5 methyl 4,6-O-benzylidene-2-deoxy-2-fluoro-α-D-allopyranoside 
• 228850-09-7 methyl 3-O-acetyl-4,6-O-benzylidene-2-dexoxy-2-fluoro-α-D-allopyranoside 
• 228850-11-1 methyl 3-O-acetyl-4-O-benzoyl-2,6-dideoxy-2-fluoro-α-D-ribo-hex-5-enopyranoside 

Relevant academic research and scientific papers

Anthracycline glycosides of 2,6-dideoxy-2-fluoro-α-l-talopyranose

The methyl β-glycoside of the title sugar, obtained from 2-deoxy-2-fluoro-β-d-glucopyranose tetraacetate by a sequence with detailed characterization of all intermediates, was converted by acetolysis-bromination into 3,4-di-O-acetyl-2,6-dideoxy-2-fluoro-α

A concise synthesis of methyl 2,6-dideoxy-2-fluoro-β-L-talopyranoside

The 4,6-benzylidene acetal of methyl 2-deoxy-2-fluoro-α,β-D-glucopyranoside underwent inversion at C-3 via an oxidation-reduction sequence, and treatment of the derived 3-acetate with N-bromosuccinimide in carbon tetrachloride gave methyl 3-O-acetyl-4-O-b