2290-39-3Relevant articles and documents
Hydrosilylation of carbonyls over electron-enriched Ni sites of intermetallic compound Ni3Ga heterogeneous catalyst
Takayama, Tomoaki,Kariya, Rio,Nakaya, Yuki,Furukawa, Shinya,Yamazoe, Seiji,Komatsu, Takayuki
supporting information, p. 4239 - 4242 (2021/05/05)
Nanoparticulate intermetallic compound Ni3Ga supported on SiO2has emerged as a highly efficient catalyst for the hydrosilylation of carbonyls, such as aldehydes and ketones, at room temperature. Formation of electron-enriched Niviaal
Hydrosilylation of epoxides catalyzed by a cationic η1- silane iridium(iii) complex
Park, Sehoon,Brookhart, Maurice
supporting information; experimental part, p. 3643 - 3645 (2011/05/04)
Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic study shows that the epoxide undergoes isomerization to the ketone, followed by hydrosilylation.
