229014-84-0Relevant academic research and scientific papers
Enantioselective synthesis of α-hydroxyacids through oxidation of terminal alkenes with AD-mix/TEMPO
Javier Aladro,Guerra, Francisco M.,Javier Moreno-Dorado,Bustamante, Jesús M.,Jorge, Zacarías D.,Massanet, Guillermo M.
, p. 3209 - 3213 (2007/10/03)
α-Hydroxyacids can be enantioselectively prepared by means of a two- step oxidation process, involving first the asymmetric dihydroxylation of a terminal alkene and subsequent oxidation with TEMPO/NaOCl/NaClO2 in good to excellent yields. No fragmentation of the glycol intermediate was detected. (C) 2000 Elsevier Science Ltd.
An Investigation on Desilylation of Alkyl and Phenolic Silyl Ethers Using FeCl3
Saravanan, Parthasarathy,Singh, Vinod K.
, p. 565 - 567 (2007/10/03)
A variety of alkyl and phenolic TBDMS ethers have been efficiently cleaved using anhydrous FeCl3 in MeOH under mild conditions. It was found that choice of solvent is crucial for the rate of the deprotection of TBDMS ether with FeCl3.
