229021-04-9Relevant articles and documents
ortho-Thioquinones, new acceptors for the stereoselective synthesis of aryl 2-deoxy-O-glycosides
Capozzi, Giuseppe,Falciani, Chiara,Menichetti, Stefano,Nativi, Cristina,Raffaelli, Barbara
, p. 1748 - 1754 (1999)
α-Hydroxynaphthylthiophthalimide (1) is a suitable precursor of the reactive ortho-thioquinone 2, which can be generated in situ and trapped by glycals. The reaction is an inverse electron-demand [4+2] cycloaddition that occurs in a totally regioselective