22937-70-8Relevant articles and documents
Mechanochemical synthesis of a processable halide perovskite quantum dot-MOF composite by post-synthetic metalation
Bhattacharyya, Sohini,Rambabu, Darsi,Maji, Tapas Kumar
supporting information, p. 21106 - 21111 (2019/10/02)
Perovskite quantum dots (PQDs) are some of the most sought after materials for optoelectronic and photovoltaic applications. We report the mechanochemical, solvent-free synthesis of a PQD?MOF composite using a post-synthetically PbII metalated
Versatile Assembly of Metal-Coordinated Calix[4]resorcinarene Cavitands and Cages through Ancillary Linker Tuning
Pei, Wen-Yuan,Xu, Guohai,Yang, Jin,Wu, Hui,Chen, Banglin,Zhou, Wei,Ma, Jian-Fang
supporting information, p. 7648 - 7656 (2017/06/13)
We propose a design strategy for assembly of metal-coordinated calix[4]resorcinarene cavitands and cages by tuning of the ancillary linkers. Assembly of newly functionalized cavitand with angular isophthalic acid analogs affords three intriguing metal-coordinated cavitands with deep cavities, 1a-1c. Further, by mediating appropriate spacers between two isophthalic acids, two bowl-shaped cavitands are successfully joined together to produce three elegant coordination cages with tunable sizes and shapes, 2a-2c. The cavitand and cage crystals possess considerable amount of accessible porosities, as clearly established by gas adsorption measurements. Remarkably, 1a-1c also exhibit high structural flexibilities, reversibly transforming between the open-pore and the narrow-pore structures, upon removal and sorption of guest molecules, as evidenced by diffraction and gas adsorption measurements. By combining experimental studies with density functional theory (DFT) calculations, we thoroughly elucidated the mechanism of the structural transformations in response to external stimuli in this new class of flexible porous solids.
Post-synthetic metalation in an anionic MOF for efficient catalytic activity and removal of heavy metal ions from aqueous solution
Chakraborty, Anindita,Bhattacharyya, Sohini,Hazra, Arpan,Ghosh, Ashta Chandra,Maji, Tapas Kumar
supporting information, p. 2831 - 2834 (2016/02/19)
A new 3D porous anionic MOF (AMOF-1) based on ZnII and a flexible tetracarboxylate linker has been synthesized. AMOF-1 showed potential for capture and removal of toxic metal ions from aqueous solution with a detection limit in the ppm level. T
Dendrimers with alternating amine and ether generations
Pan, Yijun,Ford, Warren T.
, p. 8588 - 8593 (2007/10/03)
Dendrimers having alternating aryl benzyl ether and tertiary amine generations and up to 16 bis-(2-methoxyethyl)amine end groups and four internal tertiary amines were synthesized by sequential etherification, amidation of secondary amines, and LiAlH
A new water-soluble bowl-shaped host by metal-induced self-assembly
Lee, Sang Bok,Hong, Jong-In
, p. 4317 - 4320 (2007/10/03)
A water-soluble bowl-shaped host, M3M, which possesses a hydrophobic binding cavity for apolar guests was prepared by metal-induced self-assembly through complexation of L-serine derived hydroxy acid groups with metals. Compound S without a xylenic linker
Synthesis, Characterization, and X-ray Structure of the Ruthenium "Picnic-Basket" Porphyrins
Collman, James P.,Brauman, John I.,Fitzgerald, Jeffrey P.,Hampton, Philip D.,Naruta, Yoshinori,et al.
, p. 3477 - 3486 (2007/10/02)
The synthesis and characterization of a new class of sterically protected porphyrins, the "picnic-basket" porphyrins, are presented.These tetraarylporphyrins, which were prepared as cytochrome P-450 active-site analogues, bear a rigid superstucture on one face of the porphyrin macrocycle.The cavity defined by the appended superstructure may be readily varied in size, chirality, and functionality.In addition, the synthesis and characterization, including an X-ray structure, of several ruthenium picnic-basket porphyrin carbonyl complexes are reported.The regiochemistry of axial ligation in these ruthenium derivatives has been determined by 1H NMR spectroscopy.