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1,3-Benzenedicarboxylic acid, 5,5'-[1,4-phenylenebis(methyleneoxy)]bis- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 22937-70-8 Structure
  • Basic information

    1. Product Name: 1,3-Benzenedicarboxylic acid, 5,5'-[1,4-phenylenebis(methyleneoxy)]bis-
    2. Synonyms:
    3. CAS NO:22937-70-8
    4. Molecular Formula: C24H18O10
    5. Molecular Weight: 466.401
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 22937-70-8.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1,3-Benzenedicarboxylic acid, 5,5'-[1,4-phenylenebis(methyleneoxy)]bis-(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1,3-Benzenedicarboxylic acid, 5,5'-[1,4-phenylenebis(methyleneoxy)]bis-(22937-70-8)
    11. EPA Substance Registry System: 1,3-Benzenedicarboxylic acid, 5,5'-[1,4-phenylenebis(methyleneoxy)]bis-(22937-70-8)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 22937-70-8(Hazardous Substances Data)

22937-70-8 Usage

Chemical structure

1,3-Benzenedicarboxylic acid, 5,5'-[1,4-phenylenebis(methyleneoxy)]bis-

Physical state

White crystalline solid

Uses

a. Production of polymers (e.g., polyesters and alkyd resins)
b. Key intermediate in the production of polyethylene terephthalate (PET)
c. Manufacturing of fiberglass insulation, automotive parts, and packaging materials
d. Chemical intermediate in the production of various other industrial chemicals
e. Applications in the pharmaceutical and agricultural industries

Appearance

White crystalline solid

Chemical properties

a. Acidic (due to the presence of carboxylic acid groups)
b. Can undergo esterification and other reactions involving carboxylic acid groups

Industrial applications

Widely used in the production of plastics, textiles, and other materials

Safety

Handle with care, as it may cause irritation to skin, eyes, and respiratory system

Solubility

Soluble in water and some organic solvents (e.g., ethanol, methanol)

Melting point

High melting point, which is useful for its applications in polymer production and other industrial processes.

Check Digit Verification of cas no

The CAS Registry Mumber 22937-70-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,2,9,3 and 7 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 22937-70:
(7*2)+(6*2)+(5*9)+(4*3)+(3*7)+(2*7)+(1*0)=118
118 % 10 = 8
So 22937-70-8 is a valid CAS Registry Number.

22937-70-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 5,5′-phenylenebis(methylene)-1,1′-3,3′-(benzene-tetracarboxylic acid)

1.2 Other means of identification

Product number -
Other names 5,5'-(1,4-phenylenebis(methylene))bis(oxy)-diisophthalic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:22937-70-8 SDS

22937-70-8Downstream Products

22937-70-8Relevant articles and documents

Mechanochemical synthesis of a processable halide perovskite quantum dot-MOF composite by post-synthetic metalation

Bhattacharyya, Sohini,Rambabu, Darsi,Maji, Tapas Kumar

supporting information, p. 21106 - 21111 (2019/10/02)

Perovskite quantum dots (PQDs) are some of the most sought after materials for optoelectronic and photovoltaic applications. We report the mechanochemical, solvent-free synthesis of a PQD?MOF composite using a post-synthetically PbII metalated

Versatile Assembly of Metal-Coordinated Calix[4]resorcinarene Cavitands and Cages through Ancillary Linker Tuning

Pei, Wen-Yuan,Xu, Guohai,Yang, Jin,Wu, Hui,Chen, Banglin,Zhou, Wei,Ma, Jian-Fang

supporting information, p. 7648 - 7656 (2017/06/13)

We propose a design strategy for assembly of metal-coordinated calix[4]resorcinarene cavitands and cages by tuning of the ancillary linkers. Assembly of newly functionalized cavitand with angular isophthalic acid analogs affords three intriguing metal-coordinated cavitands with deep cavities, 1a-1c. Further, by mediating appropriate spacers between two isophthalic acids, two bowl-shaped cavitands are successfully joined together to produce three elegant coordination cages with tunable sizes and shapes, 2a-2c. The cavitand and cage crystals possess considerable amount of accessible porosities, as clearly established by gas adsorption measurements. Remarkably, 1a-1c also exhibit high structural flexibilities, reversibly transforming between the open-pore and the narrow-pore structures, upon removal and sorption of guest molecules, as evidenced by diffraction and gas adsorption measurements. By combining experimental studies with density functional theory (DFT) calculations, we thoroughly elucidated the mechanism of the structural transformations in response to external stimuli in this new class of flexible porous solids.

Post-synthetic metalation in an anionic MOF for efficient catalytic activity and removal of heavy metal ions from aqueous solution

Chakraborty, Anindita,Bhattacharyya, Sohini,Hazra, Arpan,Ghosh, Ashta Chandra,Maji, Tapas Kumar

supporting information, p. 2831 - 2834 (2016/02/19)

A new 3D porous anionic MOF (AMOF-1) based on ZnII and a flexible tetracarboxylate linker has been synthesized. AMOF-1 showed potential for capture and removal of toxic metal ions from aqueous solution with a detection limit in the ppm level. T

Dendrimers with alternating amine and ether generations

Pan, Yijun,Ford, Warren T.

, p. 8588 - 8593 (2007/10/03)

Dendrimers having alternating aryl benzyl ether and tertiary amine generations and up to 16 bis-(2-methoxyethyl)amine end groups and four internal tertiary amines were synthesized by sequential etherification, amidation of secondary amines, and LiAlH

A new water-soluble bowl-shaped host by metal-induced self-assembly

Lee, Sang Bok,Hong, Jong-In

, p. 4317 - 4320 (2007/10/03)

A water-soluble bowl-shaped host, M3M, which possesses a hydrophobic binding cavity for apolar guests was prepared by metal-induced self-assembly through complexation of L-serine derived hydroxy acid groups with metals. Compound S without a xylenic linker

Synthesis, Characterization, and X-ray Structure of the Ruthenium "Picnic-Basket" Porphyrins

Collman, James P.,Brauman, John I.,Fitzgerald, Jeffrey P.,Hampton, Philip D.,Naruta, Yoshinori,et al.

, p. 3477 - 3486 (2007/10/02)

The synthesis and characterization of a new class of sterically protected porphyrins, the "picnic-basket" porphyrins, are presented.These tetraarylporphyrins, which were prepared as cytochrome P-450 active-site analogues, bear a rigid superstucture on one face of the porphyrin macrocycle.The cavity defined by the appended superstructure may be readily varied in size, chirality, and functionality.In addition, the synthesis and characterization, including an X-ray structure, of several ruthenium picnic-basket porphyrin carbonyl complexes are reported.The regiochemistry of axial ligation in these ruthenium derivatives has been determined by 1H NMR spectroscopy.

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