229471-34-5Relevant academic research and scientific papers
Phenolate-induced intramolecular ring-opening cyclization of: N -tosylaziridines: Access to functionalized benzoxacycles
Devi, Runjun,Das, Jonali,Sarma, Bipul,Das, Sajal Kumar
, p. 5846 - 5858 (2018/08/22)
Phenolate-induced, diastereo- and regioselective intramolecular exo-tet ring-opening cyclization of N-tosylaziridines has been achieved for the first time. The N-tosylaziridine substrates bearing a tethered (ortho-(tert-butyldimethylsiloxy))aryl substitue
Asymmetric palladium(0)-mediated synthesis of 2-vinylchroman
Labrosse, Jean-Robert,Poncet, Cecilia,Lhoste, Paul,Sinou, Denis
, p. 1069 - 1078 (2007/10/03)
Optically active 2-vinylchroman was synthesized from the corresponding hydroxy allylic carbonate by palladium-catalyzed cyclization in the presence of various chiral ligands. Enantioselectivity of up to 53% was obtained using NMDPP as the chiral phosphine
