230293-82-0Relevant academic research and scientific papers
Reactions of complex ligands 85: Chiral quinoid and hydroquinoid [2.2]metacyclophanes via chromium-mediated intramolecular benzannulation
Doetz,Gerhardt
, p. 223 - 228 (1999)
A meto-alkynyl (chromium alkenylcarbene) functionalized benzene 5 is synthesized in a six-step sequence starting from 3-bromomethyliodobenzene. Upon gentle warming in tetrahydrofuran methoxy[alkynylaryl(alkenyl)carbene complex 5 undergoes an intramolecula
