23037-20-9

Usage

InChI:InChI=1/C10H18N2O/c1-8(2)5-10(13,7-11)6-9(3,4)12-8/h12-13H,5-6H2,1-4H3

Upstream product

• 826-36-8 2,2,6,6-Tetramethyl-4-piperidone 
• 151-50-8 potassium cyanide 
• 75-86-5 2-hydroxy-2-methylpropanenitrile 

Downstream Products

• 65402-65-5 4-hydroxy-2,2,6,6-tetramethyl-piperidine-4-carboxylic acid 

Relevant academic research and scientific papers

Synthesis of a novel spirobisnitroxide polymer and its evaluation in an organic radical battery

A straightforward synthesis of a novel spirobisnitroxide 6 has been developed. Cyclovoltammetry of 6 revealed two distinct reversible oxidation/reduction steps separated by ca. 740 m V indicating the formation of the corresponding oxoammonium cations. Rhodium-catalyzed polymerization of 6 afforded the polyacetylene polymer 7 bearing the pending spirobisnitroxide groups. Additionally, cross-linked 7 was prepared in the presence of 3 mol % of N, N′-diprop-2-ynyl-oxalamidc. If oxidation of both nitroxide groups is considered, 7 possesses an unprecedented high theoretical charge capacity of 174 mA h g-1. Evaluation of the cross-linked polymer 7 as a cathode material for an organic radical battery showed very good cycling stability when the potential was kept below the oxidation potential of the five-membered nitroxide subunit of 6. A presumable irreversible degradation of the polymeric backbone of 7 occurred at higher potentials, limiting the experimentally obtained charge capacity to 73 m A h g-1.

Imidazolidinone nitroxides as electrode materials for energy storage devices

The invention relates to a an electrical energy storage device, such as a capacitor or a secondary battery, utilizing as active element the oxidation and reduction cycle of a sterically hindered imidazolidinone nitroxide radical. Further aspects of the invention are a method for providing such an energy storage device, the use of the respective compounds as active elements in energy storage devices and selected novel imidazolidinone nitroxide compounds.