23062-62-6

Basic information

• Product Name: Bicyclo[2.2.2]octane, 1-phenyl-
• CAS NO: 23062-62-6
• Molecular Formula: C14H18
• Molecular Weight: 186.297
• Mol File: 23062-62-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.2]octane, 1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.2]octane, 1-phenyl-(23062-62-6)
• EPA Substance Registry System: Bicyclo[2.2.2]octane, 1-phenyl-(23062-62-6)

Safety Data

• Hazardous Substances Data: 23062-62-6(Hazardous Substances Data)

Upstream product

• 20534-58-1 bicyclo[2.2.2]octan-1-ol 
• 71-43-2 benzene 
• 58143-90-1 Acetic acid 1-((1S,4R)-4-phenyl-bicyclo[2.2.2]oct-5-en-2-yl)-ethyl ester 
• 58143-91-2 1-((1S,4R)-4-Phenyl-bicyclo[2.2.2]oct-5-en-2-yl)-ethanol 
• 58143-92-3 5-Acetyl-1-phenyl-bicyclo<2.2.2>oct-2-en 
• 58143-94-5 3-Acetoxy-1-phenyl-bicyclo <2.2.2> octan 
• 58143-93-4 3-Acetyl-1-phenyl-bicyclo<2.2.2>octan 
• 58143-88-7 4-Crotyl-4-phenyl-cyclohex-2-en-1-ol 
• 58143-68-3 4-Crotyl-4-phenylcyclohex-2-en-1-on 
• 58143-95-6 4-Phenyl-bicyclo <2.2.2> octan-2-ol 
• 2064-02-0 1-(Hydroxymethyl)bicyclo<2.2.1>heptane 
• 21245-44-3 Bicyclo<2.2.2>octan-1-peroxycarbonsaeure-tert-butylester 
• 58143-96-7 4-Phenyl-bicyclo<2.2.2>octan-2-on 
• 714-68-1 1-bromo-4-phenylbicyclo<2.2.2>octane 

Downstream Products

• 23042-16-2 1-(4-Amino-2-nitrophenyl)-bicyclo<2.2.2>octan 
• 23062-69-3 1-(p-aminophenyl)bicyclo<2.2.2>octane 
• 23042-17-3 1-(o-Nitro-phenyl)-bicyclo<2.2.2>octan 
• 52380-61-7 p-Bicyclo<2.2.2>octan-1-ylacetophenon 
• 81974-62-1 1-(4-bromophenyl)bicyclo<2.2.2>octane 
• 23042-15-1 1-(2,4-Dinitro-phenyl)-bicyclo<2.2.2>octan 
• 23062-68-2 1-(4-nitro-phenyl)-bicyclo(2.2.2)octane 

Relevant articles and documents

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Molecular Rods: Synthesis and Properties

Our earlier synthetic methodology affording bicyclooctyl -rod and -rod systems proved inadequate for -rods.New synthetic approaches were developed, and - and -rod molecules were obtained.Sodium-potassium coupling was employed to afford the longer rod units.A radical anion approach gave lower yields.Hybrid rods with aromatic rings interposed were also synthesized.Rods of 9.2-, 9.7-, 13.4-, 13.9-, and 18.2-Angstroem length were included in this study.Consideration of rod chirality suggests each bicyclooctane rod unit to be stereogenic, either P (clockwise) or M (anticlockwise).Thus, in a -rod there are enantiomers and in a -rod there are diastereomers.Molecular mechanics treatment of rod stereoisomerization was carried out.Interconversion of enantiomers of the -rod and diastereomers of the -rods should be very rapid at room temperature.X-ray analysis of the 4,4'-dimethoxy--rod reveals an achiral conformation.AM1 quantum mechanics computations were carried out on -rod radical cations and bridgehead cations.