230620-79-8Relevant academic research and scientific papers
Synthesis and structural characterization of Mo2(μ-SC6H4-Cl-p) 2(μ-dppm)(CO)6 and [(dppm)(CO)2Mo(μ-SC6H4-Cl-p) 2Mo(O)]2(μ-SC6H4-Cl-p) 2(μ-O) and electrochemical property of Mo2(μ-SC6H4-Cl-p) 2
Pan, Guohua,Zhuang, Botao,He, Lingjie,Chen, Jiutong,Lu, Jiaxi
, p. 313 - 319 (1999)
Dimolybdenum(I) compound Mo2(μ-SC6H4-Cl-p)2(|.i-dppm)(CO)6 (1), (dppm = (C6H5)2PCH2P(C6H 5)2), and a trace unexpected mixed-valence tetranuclear molybdenum compound [(dppm)(CO)2Mo(μ-SC6H4-Cl-p) 2Mo(O)]2(μ-SC6H4-Cl-p) 2(μ-O) (2) were obtained from the reaction of Mo2(μ-SC6H4-Cl-p)2(CO)8 with dppm in CH2Cl2. The crystal structures of the two compounds have been determined by X-ray diffraction studies. 1: monoclinic, P2(1)/n, a = 13.1082(3), b = 23.9584(4), c = 14.8510(2) A, β = 105.865(1)°, V = 4486.32(14) A3, Z = 4, 9859 unique data, R1 = 0.0805, wR2 = 0.1076. 2·CH2Cl2: monoclinic, C2/c, a = 22.0955(13), b = 19.1563(11), c = 25.1981(14) A, β = 112.243(1)°, V = 9871.9(1) A3, Z = 4, 7053 unique data, R1 = 0.0450, wR2 = 0.1222. The cyclic voltammetry (CV) measurement for 1 showed a reversible two-electron transfer in a single step.
