230646-79-4

Upstream product

• 230646-77-2 5-(tert-butyl-dimethyl-silanyloxy)-2-methyl-hexahydro-pyrrolo[1,2-b]isoxazole-3-carbothioic acid S-propyl ester 
• 150931-64-9 (4R)-4-(t-butyldimethylsilyloxy)-1-pyrroline N-oxide 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 230646-78-3 (2R,3S)-2-[(2S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-pyrrolidin-2-yl]-3-hydroxy-thiobutyric acid S-propyl ester 

Downstream Products

• 230646-81-8 3-(tert-butyl-diphenyl-silanyloxy)-2-(4-oxo-pyrrolidin-2-yl)-thiobutyric acid S-propyl ester 
• 230646-80-7 (2R,3S)-3-(tert-Butyl-diphenyl-silanyloxy)-2-((2S,4R)-4-hydroxy-pyrrolidin-2-yl)-thiobutyric acid S-propyl ester 

Relevant academic research and scientific papers

Kinetic resolution of diiron acyl complexes - An approach to asymmetric bicyclic β-lactams

Kinetic resolution is achieved in the reaction of racemic diiron complexes like 1 with the chiral nitrone (-)-2. Oxidative removal of the metal and reductive cleavage of the N-O bond provides β-amino acids. This sequence was used in the synthesis of β-ami