2309-35-5Relevant academic research and scientific papers
Nickel-Catalyzed Direct Synthesis of Aryl Olefins from Ketones and Organoboron Reagents under Neutral Conditions
Lei, Chuanhu,Yip, Yong Jie,Zhou, Jianrong Steve
supporting information, p. 6086 - 6089 (2017/05/08)
Nickel-catalyzed addition of arylboron reagents to ketones results in aryl olefins directly. The neutral condition allows acidic protons of alcohols, phenols, and malonates to be present, and fragile structures are also tolerated.
SYNTHESIS AND LIQUID CRYSTAL PROPERTIES OF SOME 3-ARYLCHOLEST-2-ENES AND 3-ARYLCHOLEST-3,5-DIENES.
Verbit,Pinhas,Hudec
, p. 159 - 165 (2007/10/02)
A series of mesogenic 3-arylcholest-2-enes and 3-arylcholest-3,5-dienes were prepared. All members of the monoene and diene steroid series exhibited enantiotropic cholesteric mesophases. The broadest mesophase range was 90 degree , found for para-methoxyphenylcholest-2-ene.
Asymmetric Induction in Liquid Crystals: Optically Active trans-Cyclooctene from Hofmann Elimination in New Cholesteric Mesophases
Seuron, Patrick,Solladie, Guy
, p. 715 - 719 (2007/10/02)
Optically active trans-cyclooctene was obtained by Hofmann elimination of trimethylcyclooctyl ammonium hydroxide in new cholesteric liquid crystals.The extent of asymmetric induction rose 7 percent.Enantiomeric equilibration of racemic trans-cyclooctene in cholesteric medium, at 180 deg C, leads to a 2 percent enantiomeric excess.These asymmetric induction results are interpreted in terms of solute-solvent interactions enhanced by the local ordering of the mesophase.
