23099-15-2Relevant academic research and scientific papers
REACTION OF STEREOISOMERIC BICYCLIC α-OXIDES WITH LITHIUM ALUMINUM HYDRIDE
Kas'yan, L. I.,Zefirov, N. S.,Gnedenkov, L. Yu.,Stepanova, N. V.,Shashkov, A. S.,Cherepanova, E. G.
, p. 1047 - 1051 (2007/10/02)
The direction of the reactions of stereoisomeric epoxides and diepoxides, containing the norbornane fragment, with lithium aluminum hydride was studied.It was shown that the epoxide ring in the norbornane fragment is completely inert in the reduction reaction, independent of its configuration.For dioxides containing various types of epoxide rings, the rings in the substituent, and not in the norbornane fragment, undergo opening.
