23141-61-9

Basic information

• Product Name: 6-METHYL-5-NITROQUINOLINE
• Synonyms: 5-Nitro-6-methylquinoline;Quinoline, 6-methyl-5-nitro-;6-METHYL-5-NITROQUINOLINE;LABOTEST-BB LT00454049;6-Methyl-nitro-quinoline
• CAS NO: 23141-61-9
• Molecular Formula: C₁₀H₈N₂O₂
• Molecular Weight: 188.18
• EINECS: 245-447-4
• Product Categories: Building Blocks;Heterocyclic Building Blocks;Quinolines;Building Blocks;C8 to C10;Chemical Synthesis;Heterocyclic Building Blocks
• Mol File: 23141-61-9.mol
• Article Data: 3

Chemical Properties

• Melting Point: 118 °C
• Boiling Point: 330.5 °C at 760 mmHg
• Flash Point: 153.7 °C
• Appearance: /
• Density: 1.298 g/cm³
• Vapor Pressure: 0.00015mmHg at 25°C
• Refractive Index: 1.661
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• PKA: 3.04±0.15(Predicted)
• BRN: 154688
• CAS DataBase Reference: 6-METHYL-5-NITROQUINOLINE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-METHYL-5-NITROQUINOLINE(23141-61-9)
• EPA Substance Registry System: 6-METHYL-5-NITROQUINOLINE(23141-61-9)

Safety Data

• Hazard Codes: Xn
• Statements: 68-41-37/38-22
• Safety Statements: 26-36/37/39-39
• RIDADR: UN 2811 6.1/PG 3
• WGK Germany: 3
• Hazardous Substances Data: 23141-61-9(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 23141-61-9 differently. You can refer to the following data:
1. 6-Methyl-5-nitroquinoline is a starter for fused indoles.1
2. Starter for fused indoles.

InChI:InChI=1/C10H8N2O2/c1-7-2-3-8-6-11-5-4-9(8)10(7)12(13)14/h2-6H,1H3

Upstream product

• 1050267-77-0 2-(5-nitroquinolin-6-yl)acetic acid 
• 91-62-3 6-methylquinoline 

Downstream Products

• 50358-35-5 5-amino-6-methylquinoline 
• 116529-84-1 6-methyl-quinolin-5-ol 
• 233-36-3 1H-pyrrolo[2,3-f]quinoline 
• 181283-83-0 5-aminoquinoline-6-carboxylic acid 

Relevant articles and documents

Selective ortho methylation of nitroheteroaryls by vicarious nucleophilic substitution

(Chemical Equation Presented) An efficient and scalable three-step one-pot approach to 6-methyl-5-nitroisoquinoline (1) from inexpensive 5-nitroisoquinoline, utilizing the vicarious nucleophilic substitution (VNS) as a key step, is described. The optimized reaction conditions can be applied to a limited number of other aromatic and heteroaromatic nitro compounds. Attempts to understand the observed selectivity in the VNS step led to the discovery of two new reaction pathways under VNS conditions, one leading to an isoxazole and the other resulting in the formal cyclopropanation of an aromatic nitro compound.

4-Hetaroylpyrazol derivatives and the use thereof as herbicides

Hetaroyl derivatives of the formula I where: R1and R2are each hydrogen, nitro, halogen, cyano, thiocyanato, hydroxyl, mercapto, C1-C6-alkyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl or C1-C6-alkoxysulfonyl, where the last 6 radicals may be substituted and/or functionalized; phenyl, phenoxy, phenylthio, phenylsulfinyl or phenylsulfonyl, where the last 5 radicals may be substituted; Z is an unsubstituted or substituted four-membered unsaturated, partially or fully saturated chain consisting of three carbons and one nitrogen; Q is unsubstituted or substituted hydroxypyrazole linked at position 4; and their agriculturally useful salts. A process for preparing the hetaroyl derivatives, compositions comprising them, and the use of these derivatives or these compositions comprising them for controlling undesirable plants.